Figure 4-3: Computer model of gases in tank: approach to steady-state

Headspace height and water depth

both 0.1

m

Surface area of headspaces

0.11

m2

Flow rate into /out of A

2

ml s-1

Flow rate into /out of C

2

ml s-1

Transfer velocity for Sc= 600

5

cm hr-1

Schmidt number dependence

- 0.5

"n"

Water temperature

288

K

Salinity

35

%o

Air pressure

1

atm

Air temperature

293

K

Carbonate Alkalinity

0.0023

mol kg-1

Initial pCO2 in all headspaces

450

ppm

Initial pCO2 in water

350

ppm

pCO2 in air entering headspace A

1000

ppm

pCO2 in air entering headspace C

20

ppm

Error in pCO2 measurement

2

ppm

pSF6 in air entering headspace A

100

parts per trillion

pSF6 in air entering headspace C

10

parts per trillion

Error in SF6 measurement

1

parts per trillion

Time interval for calculations

10

s

Screen width

24

hr